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Enolates Go Radical. Stereoselective Radical Alkylation Reactions of Titanium Enolates from N-Acyl Oxazolidinones with Carboxylic Acid Derivatives. Synthesis of Umuravumbolide

Pérez Palau, Marina (Date of defense: 2022-07-08)

This thesis consists in the development of a new methodology of α-alkylation of carbonyl compounds and its application to the synthesis of small molecules with therapeutic interest. In this context, the ...

Reacciones directas y estereoselectivas de N-aciltioimidas quirales catalizadas por complejos de níquel(II). Síntesis de derivados de la anti ß-hidroxitirosina

Fernández-Valparís Morán, Javier (Date of defense: 2019-07-15)

En la presente tesis doctoral se ha desarrollado y expandido la metodología estereoselectiva, catalítica y de tipo directa en la cual enolatos de níquel(II) de N-acil tiazolidintionas quirales reaccionan ...

The development of new, direct and asymmetric Ni(II) catalysed carbon-carbon bond forming reactions and their application to total synthesis

Kennington, Stuart (Date of defense: 2020-12-21)

This thesis focuses on the search for new methodologies for the direct, stereoselective and catalytic formation of carbon-carbon bonds through the formation of chiral nickel(II) enolate species and the ...

Titanium(IV) enolate chemistry applied to the stereoselective construction of C–C and C–O bonds. New ionic and radical processes

Gómez Palomino, Alejandro (Date of defense: 2018-11-27)

In the present Thesis we continued a previous study of the nucleophilic character of titanium(IV) enolates. Particularly,we focused our attention on the analysis of substrate-controlled Michael additions ...

Reacciones directas de la N-azidoacetil-1,3-tiazolidin-2-tiona catalizadas por complejos quirales de níquel(II) para la construcción enantioselectiva de enlaces carbono-carbono. Síntesis de la lacosamida y derivados de la β-hidroxifenilalanina

Flores Teloxa, Saúl (Date of defense: 2020-12-01)

En esta Tesis Doctoral se han explorado y optimizado nuevas metodologías enantioselectivas y directas de formación de enlaces carbono-carbono catalizadas por complejos quirales de níquel(ll). ...

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Enolates Go Radical. Stereoselective Radical Alkylation Reactions of Titanium Enolates from N-Acyl Oxazolidinones with Carboxylic Acid Derivatives. Synthesis of Umuravumbolide

Reacciones directas y estereoselectivas de N-aciltioimidas quirales catalizadas por complejos de níquel(II). Síntesis de derivados de la anti ß-hidroxitirosina

The development of new, direct and asymmetric Ni(II) catalysed carbon-carbon bond forming reactions and their application to total synthesis

Titanium(IV) enolate chemistry applied to the stereoselective construction of C–C and C–O bonds. New ionic and radical processes

Reacciones directas de la N-azidoacetil-1,3-tiazolidin-2-tiona catalizadas por complejos quirales de níquel(II) para la construcción enantioselectiva de enlaces carbono-carbono. Síntesis de la lacosamida y derivados de la β-hidroxifenilalanina

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Enolates Go Radical. Stereoselective Radical Alkylation Reactions of Titanium Enolates from N-Acyl Oxazolidinones with Carboxylic Acid Derivatives. Synthesis of Umuravumbolide

Reacciones directas y estereoselectivas de N-aciltioimidas quirales catalizadas por complejos de níquel(II). Síntesis de derivados de la anti ß-hidroxitirosina

The development of new, direct and asymmetric Ni(II) catalysed carbon-carbon bond forming reactions and their application to total synthesis

Titanium(IV) enolate chemistry applied to the stereoselective construction of C–C and C–O bonds. New ionic and radical processes

Reacciones directas de la N-azidoacetil-1,3-tiazolidin-2-tiona catalizadas por complejos quirales de níquel(II) para la construcción enantioselectiva de enlaces carbono-carbono. Síntesis de la lacosamida y derivados de la β-hidroxifenilalanina