Mostrando ítems 1-20 de 40
Costas Salgueiro, Miquel (Fecha de defensa: 1999-02-26)
This thesis is organized in seven independent chapters: I) a description of the structure and reactivity of the metalloproteins of copper and iron which deal with the oxygen processing into living organisms; II) an study ...
López Lastra, Adrián (Fecha de defensa: 2020-07-28)
Polymers are one of the most used compounds in the chemical industry because they have application in a wide variety of products for daily use. Polymer preparation and its analysis is a very active field of research in ...
Gómez Martín, Laura (Fecha de defensa: 2010-06-04)
La gran eficiència, selectivitat i les condicions suaus exhibides per les reaccions que tenen lloc al centre actiu de les metal·looxigenases són la font d'inspiració per la present dissertació. Amb l'objectiu de dissenyar ...
Magallón Gubau, Carla (Fecha de defensa: 2022-05-16)
Nowadays, one of the main goals in organic chemistry and fine industry is the development of new synthetic methodologies for the preparation of life-relevant products in a sustainable manner. The use of first-row ...
Dantignana, Valeria (Fecha de defensa: 2020-12-03)
Selective oxidation of C-H bonds is an important reaction, as it can disclose novel synthetic strategies to get functionalized products through efficient paths. Nonetheless, due to the inert character of C-H bonds, the use ...
Prat Casellas, Irene (Fecha de defensa: 2013-06-14)
The functionalization of hydrocarbons in a sustainable manner is one of the main challenges for chemists. Their abundance in nature as natural gas or crude oil makes them the most convenient chemical feedstock. The oxidation ...
Guerrero Troyano, Isabel (Fecha de defensa: 2022-03-13)
This thesis studies the behavior of different metallacarboranes such as Na[Co(C2B9H11)2] Na[1] and their chlorinated derivatives, Na[3,3’-Co(8-Cl-1,2-C2B9H10)2] Na[Cl2-1] i Na[3,3’-Co(8,9,12-Cl3-1,2-C2B9H8)2] Na[Cl6-1], ...
Cianfanelli, Marco (Fecha de defensa: 2021-12-03)
In this thesis we developed a protocol for the intramolecular oxidation of prochiral secondary C-H bonds in which carboxylic acids, acting as directing groups for the oxidant species, promoted a highly site-selective and ...
Capdevila Güell, Lorena (Fecha de defensa: 2022-07-22)
The development of new methodologies for the construction of complex molecules is one of the principal objectives in synthetic organic chemistry. Although huge advances have been made on cross-coupling reactions, there is ...
Planas Fàbrega, Oriol (Fecha de defensa: 2018-02-23)
This Ph.D. dissertation describes the synthesis and characterization of bench-top stable aryl-Co(III) organometallic species using commercially available cobalt(II) salts and a macrocyclic model substrate. Special attention ...
Roldán Gómez, Steven (Fecha de defensa: 2020-01-14)
During the last decades, computational chemistry has become a resourceful tool in the quest to understand and predict the mechanism and the reactivity of chemical systems. This is especially true in the area of ...
Ferrer Vall-llosada, Íngrid (Fecha de defensa: 2015-07-16)
In this thesis we present the synthesis and characterization of different types of ruthenium complexes containing N-donor ligands together with dmso, Cl and H2O ligands, along with their complete characterization through ...
Manrique Salas, Ester (Fecha de defensa: 2018-10-22)
In this thesis we present the synthesis and characterization of different types of ruthenium complexes containing N-donor ligands together with monodentate ligands, along with their complete characterization through s ...
Call Quintana, Arnau (Fecha de defensa: 2016-12-13)
The increasing need for more efficient synthetic methods and sustainable processes for fuel and high-value organic molecules production can be seen as one of the major challenging goals for the future. Nature has developed ...
Font Rubio, Pau (Fecha de defensa: 2023-10-06)
Homogeneous reactions catalyzed by gold have mainly been developed in the past two decades, stemming from the proneness of Au(I) and Au(III) complexes to coordinate and activate carbon-carbon multiple bonds towards a ...
Sabeña Vila, Gerard (Fecha de defensa: 2017-06-23)
In this work we have prepared octahedral non - heme iron species in high oxidation states. Iron (IV) - oxo and iron (IV) - imido complexes based on triazacyclononane scaffold had been synthesised and all of them had been ...
Vicens Serra, Laia (Fecha de defensa: 2023-07-18)
Most of the organic molecules used in chemical industry (and their synthetic precursors) contain oxygen atoms in their structure. One of the most convenient methods for the preparation of oxygenated compounds is the ...
Arbusé Font, Arnau (Fecha de defensa: 2020-11-12)
Macrocyclic ligands and its complexes have been studied in a wide variety of fields, among them bioinorganic chemistry. In this work it is reported three studies of macrocyclic species under three points of view. Firstly, ...
Font Molins, Marc (Fecha de defensa: 2015-02-13)
Aryl-Cu(III) species have been often implicated as the intermediate species that operate Ullmann-type couplings. However, such species have long remained elusive and the fundamental pathways that govern Ullmann-type ...
Rich Masallera, Jordi (Fecha de defensa: 2012-06-08)
The catalytic asymmetric oxidation of alkenes has special interest from both industrial and academic points of view. For this reason, catalysts able to perform these reactions in a faster and more effective manner have ...