Now showing items 57-76 of 86
Salomó i Prat, Ernest (Date of defense: 2018-10-19)
Asymmetric hydrogenation of double bonds by means of organometallic catalysis is a powerful tool for organic synthesis; it is an efficient and simple method to produce valued chiral compounds. Among the many different ...
Gallen Ortiz, Albert (Date of defense: 2019-02-01)
The Thesis deals with the preparation, coordination chemistry and use in asymmetric homogeneous catalysis of several optically pure P-stereogenic ligands containing a tert-butylmethylphosphino fragment. In the first part ...
Rojo Solé, Josep Maria (Date of defense: 2022-11-02)
[eng] P-Stereogenic ligands have demonstrated to be highly efficient for asymmetric catalysis, especially in metal-catalyzed asymmetric hydrogenation reactions. Among them, those bearing bulky substituents at phosphorus ...
Mancinelli, Andrea (Date of defense: 2017-04-21)
The development of selective methods for the direct conversion of carbon−hydrogen bonds into carbon-heteroatom and carbon−carbon bonds remains a critical challenge in organic chemistry. An interesting approach to address ...
Escriche Tur, Luis (Date of defense: 2016-11-21)
The main objective of this work is the synthesis of manganese compounds and hybrid materials that may be relevant from a bioinorganic and magnetic point of view. The developed strategy comprises three main steps that form ...
Llorens Palomo, Lluís (Date of defense: 2019-10-28)
Cucurbiturils are known to present potential applications in molecular recognition, self- assembly, and nanotechnology. The discovery of ultra-high affinity CB–guest complexes with binding constant values similar than those ...
Lobo Ruiz, Ariadna (Date of defense: 2019-05-10)
Peptides and proteins are essential substances for living organisms, as they can be found in every cell and tissue and are involved in many biological and physiological processes. Given their intrinsic properties and their ...
Flores Teloxa, Saúl (Date of defense: 2020-12-01)
En esta Tesis Doctoral se han explorado y optimizado nuevas metodologías enantioselectivas y directas de formación de enlaces carbono-carbono catalizadas por complejos quirales de níquel(ll). Esencialmente, se han estudiado ...
Fernández-Valparís Morán, Javier (Date of defense: 2019-07-15)
En la presente tesis doctoral se ha desarrollado y expandido la metodología estereoselectiva, catalítica y de tipo directa en la cual enolatos de níquel(II) de N-acil tiazolidintionas quirales reaccionan con un amplio grupo ...
Kumari, Sarika (Date of defense: 2023-12-20)
[eng] Since the last two decades, nanotechnology has been revolutionary for representing small solutions to the big problems. Nanoscience and Nanotechnology spread from the area of Electronics, Energy and Environment to ...
Cuadrado Santolaria, Alba (Date of defense: 2019-10-18)
En los últimos años se han llevado a cabo intensas investigaciones dentro del campo de los materiales orgánicos semiconductores, principalmente enfocados a su aplicación en dispositivos electrónicos y optoelectrónicos como ...
Agramunt Pi, Jordi (Date of defense: 2019-11-08)
2,2-Disubstituted cyclopent-4-ene-1,3-diones (CPDs), which have been as non-hydrolysable maleimide analogs, have been found to possess an unexpected reactivity with N-terminal cysteines. Whilst maleimides react in an ...
Rosado Piquer, Lidia (Date of defense: 2019-10-04)
L’obtenció de dispositius per aplicacions tecnològiques a la nanoescala implica l’ús de molècules que permeten la miniaturització d’aquests, aconseguint així més eficiència en menys espai. Les molècules que s’utilitzen ...
González García, Jordi (Date of defense: 2016-09-29)
En el present treball s’han sintetitzat dos lligands divalents i tres lligands monovalents per a les proteïnes avidina i estreptavidina, i s’han determinat les corresponents constants d’associació. Els lligands divalents ...
Teruel Sánchez, Carolina (Date of defense: 2023-12-12)
[cat] Tradicionalment, els fàrmacs de baix pes molecular (PM < 500 Da), coneguts com “molècules petites”, han predominat en el tractament de les malalties humanes, encara que en les últimes dècades els productes biològics ...
Torralvo Martin, Héctor (Date of defense: 2020-09-29)
[spa] En la industria farmacéutica es común buscar procesos alternativos de producción de fármacos comerciales o a punto de entrar en el mercado. En este trabajo, y en colaboración con Esteve Química S.A., se han buscado ...
Guarnizo Franco, Anderson (Date of defense: 2016-07-21)
Se han sintetizado nanopartículas (NPs) de paladio depositadas en la superficie de nanopartículas de magnetita (MNPs) previamente modificadas con el nuevo ligando 4- mercaptofenildifenilfosfina (Sdp). Estos híbridos mostraron ...
Escolà Jané, Anna (Date of defense: 2018-11-09)
Somatostatin (SST or SRIF14) is a peptidic hormone secreted throughout the central nervous system and in the gastrointestinal tract which has anti-secretory, anti-proliferative and anti-angiogenic effects. Although its ...
Darawsheh, Mohanad D. (Date of defense: 2016-11-04)
The results obtained in this thesis demonstrate the importance of supramolecular chemistry for the design of potential new SCO clusters. Starting from synthesizing the suitable ligands with suitable functional groups, novel ...
Mir Morro, Bartomeu (Date of defense: 2019-11-22)
Given the increasing interest in i-motif structures, obtaining such structures as well as detailed structural information under physiological conditions have become hot topics in the structural biology field. In this ...